B. Schulz et al., MIXED MOBILE ION EFFECT - A NUMERICAL STUDY ON THE BASIS OF A MODIFIED 2-SPIN FACILITATED KINETIC ISING-MODEL, Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics, 58(3), 1998, pp. 3368-3371
A numerical simulation on the basis of a modified two-spin facilitated
kinetic Ising model for the longstanding problem of the mixed mobile
ion effect (or mixed alkali effect) in glasses is presented. The essen
tial idea is an internal dynamical interaction between the cation moti
on and the dynamics of the cooperative regions of the glass. This inte
raction leads to a strong variation of the de conductivity versus the
composition ratio f of the cations contained in the glass. Both the de
pendence on temperature and the dependence on the composition ratio ca
n be obtained in good agreement with experimental measurements.