PREPARATION AND CHARACTERIZATION OF FACIAL AND MERIDIONAL ISOMERS OF IAMINE-N,N'-DI-3-PROPIONATO)(GLYCINATO)COBALT(III) SEMIHYDRATE

Authors
SABO TJ GRGURIC SR MINIC DM TRIFUNOVIC SR
Citation
Tj. Sabo et al., PREPARATION AND CHARACTERIZATION OF FACIAL AND MERIDIONAL ISOMERS OF IAMINE-N,N'-DI-3-PROPIONATO)(GLYCINATO)COBALT(III) SEMIHYDRATE, Journal of coordination chemistry (Print), 44(1-2), 1998, pp. 47-54
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of coordination chemistry (Print) → ACNP
ISSN journal
00958972
Volume
44
Issue
1-2
Year of publication
1998
Pages
47 - 54
Database
ISI
SICI code
0095-8972(1998)44:1-2<47:PACOFA>2.0.ZU;2-5
Abstract
Both theoretically possible geometrical isomers, facial and meridional , of iamine-N,N'-di-3-propionato)(glycinato)cobalt(III) semi hydrate h ave been prepared by reaction of sodium uns-cis-(ethylenediamine-N, N' -di-3-propionato) (carbonato) cobaltate(III) with glycine at 75 degree s C. The complexes have been isolated chromatographically and characte rized by elemental analysis, electron absorption, infrared and nuclear magnetic spectra.