DINUCLEAR COPPER(II) COMPLEXES WITH 3-FURANCARBOXYLIC ACID AND 2-THIOPHENCARBOXYLIC ACID

Authors
PALUCHOWSKA B MAURIN JK LECIEJEWICZ J
Citation
B. Paluchowska et al., DINUCLEAR COPPER(II) COMPLEXES WITH 3-FURANCARBOXYLIC ACID AND 2-THIOPHENCARBOXYLIC ACID, Journal of coordination chemistry (Print), 44(1-2), 1998, pp. 183-192
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of coordination chemistry (Print) → ACNP
ISSN journal
00958972
Volume
44
Issue
1-2
Year of publication
1998
Pages
183 - 192
Database
ISI
SICI code
0095-8972(1998)44:1-2<183:DCCW3A>2.0.ZU;2-N
Abstract
The structures of Cu(II) 3-furancarboxylate and Cu(II) 2-thiophenate d enoted hereafter as Cu-3F and Cu-2T, respectively, were determined. Th e structures are dinuclear, bridged by bidentate ligands. The coordina tion about copper is square pyramidal. The pKa of the respective acids is a factor influencing changes in Cu-Cu distances. The differences i n hydrogen bond patterns and packing are described.