ISLAND FORMATION IN CHEMISORPTION 2 - CHEMISORPTION KINETICS

Authors
SALANOV AN BIBIN VN RUDINA NA
Citation
An. Salanov et al., ISLAND FORMATION IN CHEMISORPTION 2 - CHEMISORPTION KINETICS, Reaction kinetics and catalysis letters, 64(2), 1998, pp. 269-274
Citations number
14
Categorie Soggetti
Chemistry Physical
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
64
Issue
2
Year of publication
1998
Pages
269 - 274
Database
ISI
SICI code
0133-1736(1998)64:2<269:IFIC2->2.0.ZU;2-H
Abstract
Influence of ''direct'' and ''indirect'' pathways of dissociative chem isorption on the form of kinetic dependences theta(MCS) and S(theta) w as studied by the Monte Carlo method. Langmuir adsorption observed at S-indir/S-dir less than or equal to 0.1 gradually changes to island-me diated adsorption with an increase of the ''indirect'' adsorption cont ribution at 0.1 less than or equal to S-indir/S-dir less than or equal to 1.0 At S-indir/S-dir greater than or equal to 1.0 the island-media ted adsorption dominates: large adsorption islands arise and gradually grow.