Y. Maeda et al., SILICON NANOSTRUCTURE FABRICATION USING IR-FELS AND ITS OPTICAL-PROPERTIES, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 144(1-4), 1998, pp. 152-159
Novel silicon nanostructures were fabricated from hydrogenated amorpho
us silicon (a-Si:H) by irradiation with infrared Free Electron Lasers
(IR-FELs). SEM and XTEM observations and Raman spectra show that the f
abricated materials have nanometer or micrometer-sized complicated fib
ers (Si microfibers) including large amounts of several nanometer-size
d Si nanocrystals (nc-Si) embedded in the glassy SiO2 matrices. Size d
ependent visible photoluminescence (PL) from nc-Si in the Si microfibe
rs was observed at room temperature. The visible PL mechanism of nc-Si
and formation mechanism of the Si microfibers due to the FEL irradiat
ion are discussed. (C) 1998 Elsevier Science B.V. All rights reserved.