S. Therias et al., ELECTROCHEMICAL STUDY OF FERROCENE AND NITROXIDE DERIVATIVES INTERCALATED IN ZN-CR AND ZN-AL LAYERED DOUBLE HYDROXIDES, Journal of electroanalytical chemistry [1992], 454(1-2), 1998, pp. 91-97
Layered double hydroxides (LDH) containing the electrochemical redox a
nions ferrocene sulfonates (FcMS and FcDS) and a nitroxide radical (NO
DC) have been prepared and characterized by PXRD, IR and ESR. The elec
trochemical behaviour of these hybrid materials as well as the role of
the electrolyte anions during the oxidation process have been studied
by cyclic voltammetry. An electrochemical transfer at LDH modified el
ectrodes via an intracrystallite mechanism is confirmed. (C) 1998 Else
vier Science S.A. All rights reserved.