A NEW METHOD FOR CROSS-METATHESIS OF TERMINAL OLEFINS

Authors
OLEARY DJ BLACKWELL HE WASHENFELDER RA GRUBBS RH
Citation
Dj. Oleary et al., A NEW METHOD FOR CROSS-METATHESIS OF TERMINAL OLEFINS, Tetrahedron letters, 39(41), 1998, pp. 7427-7430
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
41
Year of publication
1998
Pages
7427 - 7430
Database
ISI
SICI code
0040-4039(1998)39:41<7427:ANMFCO>2.0.ZU;2-8
Abstract
A new method for the cross-metathesis of terminal olefins is described . Treatment of terminal olefins with 1-2 equivalents of a symmetric di substituted cis or trans olefin and 5 mol% Cl-2(PCy3)(2)Ru=CHPh (1) in dichloromethane generates the desired cross-metathesis products in go od yield. (C) 1998 Elsevier Science Ltd. AII rights reserved.