REARRANGEMENT AND PHOTOLYSIS OF AZIRIDINES IN THE ASPIDOSPERMA SERIES

Authors
HOFFMANN N HUGEL G NUZILLARD JM ROYER D
Citation
N. Hoffmann et al., REARRANGEMENT AND PHOTOLYSIS OF AZIRIDINES IN THE ASPIDOSPERMA SERIES, Tetrahedron letters, 39(41), 1998, pp. 7503-7506
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
41
Year of publication
1998
Pages
7503 - 7506
Database
ISI
SICI code
0040-4039(1998)39:41<7503:RAPOAI>2.0.ZU;2-T
Abstract
Rearrangement of aziridine I by MgBr2 gave 2-H-dihydro-17-dehydrovinca difformine 6. Photolysis transformed aziridines 1 and 11 into the new compounds 1,2-seco-1,21-cyclovincadifformine 10 and 1,2-seco-1,21-cycl otabersonine 12. (C) 1998 Elsevier Science Ltd. All rights reserved.