Lk. Aminov et al., SOME PECULIARITIES OF SPIN-LATTICE RELAXATION OF IMPURITY RARE-EARTH IONS IN CRYSTALS, CAUSED BY THE STRUCTURE DEFECTS, Applied magnetic resonance, 14(4), 1998, pp. 447-456
Citations number
25
Categorie Soggetti
Spectroscopy,"Physics, Atomic, Molecular & Chemical
The spin-lattice relaxation times for Nd3+ ions in yttrium-aluminum ga
rnets (YAG) and for Yb3+ ions in CaF2, in the low-temperature range ha
ve been measured. For the first system the temperature dependence of t
he relaxation rate is determined to a great extent by the method of sa
mple preparation. For samples grown by the method of the horizontally
oriented crystallization the dependence is described as T-l(-1) = AT(n
), n congruent to 4.7, which is an evidence of an influence of local s
tructure disordering on the relaxation. The temperature dependence of
the relaxation rate in CaF2:Yb is also ''anomalous'': T-l(-1) = AT(3.3
). The results are compared with the previous data on the relaxation i
n similar systems, and with other cases of observation of ''anomalous'
' temperature dependences. Different manifestations of the local cryst
al defects in spin-lattice relaxation are discussed.