ESR STUDY OF SOME IMINOXY FREE-RADICALS GENERATED FROM PHOSPHORYLATEDOXIMES AND DIOXIMES

Authors
ILYASOV AV VAFINA AA BREUER E HAGELE G
Citation
Av. Ilyasov et al., ESR STUDY OF SOME IMINOXY FREE-RADICALS GENERATED FROM PHOSPHORYLATEDOXIMES AND DIOXIMES, Applied magnetic resonance, 14(4), 1998, pp. 489-496
Citations number
17
Categorie Soggetti
Spectroscopy,"Physics, Atomic, Molecular & Chemical
Journal title
Applied magnetic resonance → ACNP
ISSN journal
09379347
Volume
14
Issue
4
Year of publication
1998
Pages
489 - 496
Database
ISI
SICI code
0937-9347(1998)14:4<489:ESOSIF>2.0.ZU;2-V
Abstract
The new type of phosphoniminoxy free radicals was generated electroche mically or by chemical oxidation of oximes. It was established the str ong difference of ESR parameters for isomeric Z and E forms of the rad icals. The spin distribution and its correlation with electronic and s patial characteristics of molecules as well as with intramolecular int eractions are discussed.