SLIPPAGE - AN ALTERNATIVE METHOD FOR ASSEMBLING [2]ROTAXANES

Authors
ASHTON PR BELOHRADSKY M PHILP D STODDART JF
Citation
Pr. Ashton et al., SLIPPAGE - AN ALTERNATIVE METHOD FOR ASSEMBLING [2]ROTAXANES, Journal of the Chemical Society, Chemical Communications, (16), 1993, pp. 1269-1274
Citations number
41
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
16
Year of publication
1993
Pages
1269 - 1274
Database
ISI
SICI code
0022-4936(1993):16<1269:S-AAMF>2.0.ZU;2-C
Abstract
The exploitation of size-complementarity between the macrocyclic compo nent and the stoppers of the dumbbell component of a [2]rotaxane, toge ther with stabilising noncovalent bonding interactions that create a t hermodynamic trap, have permitted the development of an alternative me thod, which can be termed slippage, for the syntheses of [2]rotaxanes in good yields.