OPTICAL AND PHOTOELECTROCHEMICAL STUDIES OF RH-SN COMPLEXES IN H2SO4 SOLUTIONS

Authors
VOLKOV SV KOLBASOV GY NECHAEVA NE KHARKOVA LB TARANETS TA
Citation
Sv. Volkov et al., OPTICAL AND PHOTOELECTROCHEMICAL STUDIES OF RH-SN COMPLEXES IN H2SO4 SOLUTIONS, Russian journal of applied chemistry, 71(4), 1998, pp. 631-633
Citations number
14
Categorie Soggetti
Chemistry Applied
Journal title
Russian journal of applied chemistry → ACNP
ISSN journal
10704272
Volume
71
Issue
4
Year of publication
1998
Pages
631 - 633
Database
ISI
SICI code
1070-4272(1998)71:4<631:OAPSOR>2.0.ZU;2-J
Abstract
The formation of a Rh-Sn binuclear complex in Rh(III) and Sn(II) sulfa te electrolytes was confirmed by spectrophotometry. Photoelectrical st udies detected a Rh-Sn charge-transfer complex on the surface of a rho dium electrode subjected to cyclic anode-cathode treatment in a tin su lfate solution. The ionization potential of this complex I-d is 11.3 e V.