G. Klarner et al., COLORFAST BLUE-LIGHT-EMITTING RANDOM COPOLYMERS DERIVED FROM DI-N-HEXYLFLUORENE AND ANTHRACENE, Advanced materials, 10(13), 1998, pp. 993
Strong colorfast blue photo- and electroluminescence is reported for r
andom high molecular weight poly(fluorene-co-anthracene)s, prepared vi
a the nickel-mediated copolymerization of the corresponding aryl dibro
mides. The incorporation of anthracene into the main chain is demonstr
ated to completely suppress excimer formation-a major drawback of many
planar pi-systems. Poly(fluorene)s are attractive as active component
s of organic light-emitting diodes (LEDs) because of their thermal and
chemical stability and exceptionally high fluorescence quantum yields
.