EVAPORATED CRYSTALLINE FILM OF PLATINUM DIMETHYLGLYOXIME WITH SHORT ONE-DIMENSIONAL METAL CHAINS

Authors
YAMAMOTO K KAMATA T YOSHIDA Y YASE K MIZUKAMI F OHTA T
Citation
K. Yamamoto et al., EVAPORATED CRYSTALLINE FILM OF PLATINUM DIMETHYLGLYOXIME WITH SHORT ONE-DIMENSIONAL METAL CHAINS, Advanced materials, 10(13), 1998, pp. 1018
Citations number
27
Categorie Soggetti
Material Science
Journal title
Advanced materials → ACNP
ISSN journal
09359648
Volume
10
Issue
13
Year of publication
1998
Database
ISI
SICI code
0935-9648(1998)10:13<1018:ECFOPD>2.0.ZU;2-9
Abstract
The self-organization of a third-order nonlinear optical metal complex , bis(dimethylglyoximato)platinum(II), Pt(dmg)(2), into one-dimensiona l chains is investigated. It is found that, upon vacuum evaporation on a KBr substrate, epitaxial crystallization of the metal complex takes place and plate-like islands are formed. Within the islands, the meta l complex is organized into oriented chains of controllable length. Th e growth process and structure are discussed from optoelectronic and s tructural points of view.