Supramolecular multilayered ferromagnets in which metal layers are int
erleaved with iminonitroxide benzoate radical anions have been synthes
ized and characterized by the authors. The structure of these novel co
mpounds (see cover) consists of stacks of alternating organic-inorgani
c layers. Long-range ferromagnetism is evidenced by magnetic and elect
roparamagnetic resonance (EPR) measurements, and shows clear interacti
on between the two sub-networks. In this respect, this new class of hy
brid magnets differs markedly from classical intercalated layer compou
nds.