Vg. Yadav et Sb. Chandalia, SYNTHESIS OF PHENETHYL ALCOHOL BY CATALYTIC-HYDROGENATION OF STYRENE OXIDE, Organic process research & development, 2(5), 1998, pp. 294-297
In the current work, phenethyl alcohol was synthesized by the hydrogen
ation of styrene oxide, which may be obtained by the oxidation of styr
ene, Conventional method of synthesis of phenethyl alcohol is by the F
riedel-Crafts alkylation of benzene by using ethylene oxide and molar
quantities of aluminum chloride. This method causes effluent disposal
problems due to the stoichiometric use of aluminum chloride as the alu
minum oxychloride formed in the process is normally not recycled, The
hydrogenation of styrene oxide was conducted by using Raney nickel cat
alyst and process conditions were established. The yield of phenethyl
alcohol obtained was 90.2% with 92% overall conversion of styrene oxid
e under suitable conditions. Styrene oxide was also synthesized in the
laboratory.