NATURE OF THE ACTIVATION OF A PD(ACAC)(2)PPH3 AND NAH2PO2-BASED METAL-COMPLEX CATALYST FOR HYDROGENATION

Authors
BELYKH LB SHMIDT FK
Citation
Lb. Belykh et Fk. Shmidt, NATURE OF THE ACTIVATION OF A PD(ACAC)(2)PPH3 AND NAH2PO2-BASED METAL-COMPLEX CATALYST FOR HYDROGENATION, Kinetics and catalysis, 39(3), 1998, pp. 349-353
Citations number
7
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
39
Issue
3
Year of publication
1998
Pages
349 - 353
Database
ISI
SICI code
0023-1584(1998)39:3<349:NOTAOA>2.0.ZU;2-0
Abstract
The role of hydrogen and unsaturated substrates in the activation of a metal complex hydrogenation catalyst based on Pd(acac)(2)PPh3 and NaH 2PO2 was considered. Deeper dephenylation of organophosphorus ligands of the palladium complex catalyst in the course of hydrogenation of un saturated derivatives was found to be the principal cause of activatio n. The role of unsaturated substrates is limited to stabilization of c atalytically active palladium complexes formed by dephenylation.