PHASE-EQUILIBRIUM AND INTERDIFFUSIONS IN SYSTEMS BASED ON POLY(CHLOROPRENE) AND ACRYLONITRILE-BUTADIENE RANDOM COPOLYMERS

Authors
CHALYKH AE RUBTSOV AE AVGONOV A ALIEV AD GROMOV VV
Citation
Ae. Chalykh et al., PHASE-EQUILIBRIUM AND INTERDIFFUSIONS IN SYSTEMS BASED ON POLY(CHLOROPRENE) AND ACRYLONITRILE-BUTADIENE RANDOM COPOLYMERS, Vysokomolekularnye soedinenia. Seria A, 40(4), 1998, pp. 596-603
Citations number
15
Categorie Soggetti
Polymer Sciences
Journal title
Vysokomolekularnye soedinenia. Seria A → ACNP
ISSN journal
05075475
Volume
40
Issue
4
Year of publication
1998
Pages
596 - 603
Database
ISI
SICI code
0507-5475(1998)40:4<596:PAIISB>2.0.ZU;2-E
Abstract
Mutual diffusion and solubility of nitrile rubbers with various compos itions in poly(chloroprene) was studied by methods of electron-probe X -ray microanalysis and transmission electron microscopy. The phase dia grams were constructed, the diffusion coefficients for the migration o f macromolecules of nitrile rubbers into poly(chloroprene) and vice ve rsa were determined, and the interphase boundaries, diffusion activati on energies, Flory--Huggins interaction parameters, and critical solub ility temperatures of components were calculated.