A field experiment examined stability and stratification in a disused
mine pit filled with 1.75 x 10(7) m(3) of water. Vertical profiles of
conductivity and temperature indicated that, due to substantial chemic
al stratification, spring and autumn overturn did not penetrate to the
base of the pit. Although parameterization indicated that double diff
usion should be expected, we found only circumstantial evidence of ass
ociated step structure. The available data suggest that groundwater in
flow created a warm salty pool of water at the base of the water colum
n, giving the appearance of a meromictic structure with a monimolimnio
n. However, this pool was not a consistent feature, suggesting both a
variable inflow and significant diffusion rates. From the temperature
data, estimates indicated that hypolimnetic vertical eddy diffusivity
varied between 1 x 10(-7) and 5 x 10(-5) m(2) s(-1). The observations
identify short-term relatively energetic internal wave events that may
have a significant impact on this value. The present study is useful
in two ways: first, it shows how pit-lakes form a natural laboratory f
or a range of processes, and second, it illustrates how these processe
s relate to diffusion parameterization. It is clear that reliable para
meterization is vital for long-term modeling required for prediction o
f water quality over decadal timescales.