SYNTHESIS AND CHARACTERIZATION OF COPPER(II) AND NICKEL(II) COMPLEXESWITH SCHIFF-BASES DERIVED FROM AROMATIC DIAMINES AND HETEROCYCLIC ALDEHYDES

Authors
SATPATHY M PRADHAN B
Citation
M. Satpathy et B. Pradhan, SYNTHESIS AND CHARACTERIZATION OF COPPER(II) AND NICKEL(II) COMPLEXESWITH SCHIFF-BASES DERIVED FROM AROMATIC DIAMINES AND HETEROCYCLIC ALDEHYDES, Journal of the Indian Chemical Society, 75(9), 1998, pp. 518-519
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Journal of the Indian Chemical Society → ACNP
ISSN journal
00194522
Volume
75
Issue
9
Year of publication
1998
Pages
518 - 519
Database
ISI
SICI code
0019-4522(1998)75:9<518:SACOCA>2.0.ZU;2-C
Abstract
Chelating ligands derived from thiophene-2-aldehyde and o-phenylenedia mine (talophen) or tn-phenylenediamine (talmphen) have been synthesize d. The complexes of Cu-II and Ni-II have been isolated. [Cu(talophen)( 2)]Cl-2, [Cu(talmphen)(2)]Cl-2, [Ni(talophen)(2)]Cl-2, [Ni(talmphen)(2 )]Cl-2 are diamagnetic and square planar, Other Cu-II and Ni-II comple xes show mu(eff) indicative of their distorted octahedral or octahedra l nature.