This report details the first observation of reflection high energy po
sitron diffraction. A 20 keV positron beam was irradiated onto a hydro
gen-terminated Si(111) surface from the [1 (1) over bar 0] and [11 (2)
over bar] directions. The zeroth Laue zone consisting of a specular a
nd diffraction spots with a shadow edge was clearly observed using a m
icrochannel plate at relatively high glancing angles (theta > 3.0 degr
ees). The rocking curve of the specular spot showed the primary Bragg
peak and the total reflection of positrons. [S0031-9007(98)07178-6].