Yp. Panarin et al., APPEARANCE OF FERRIELECTRIC PHASES IN A CONFINED LIQUID-CRYSTAL INVESTIGATED BY PHOTON-CORRELATION SPECTROSCOPY, Physical review letters, 81(13), 1998, pp. 2699-2702
Dynamic light scattering was used to examine ferrielectric liquid-crys
talline phases in porous media. Whereas in larger pores (2000 Angstrom
) ferrielectric phases were observed, they were not found in the small
est pores (200 Angstrom). Additionally, the temperatures of several ph
ase transitions were found to be suppressed in the pores relative to b
ulk. These observations have been explained by the structural aspects
of antiferroelectric liquid-crystalline materials in a confined geomet
ry. [S0031-9007(98)07214-7].