M. Michaud et al., LIFETIME OF NEGATIVE-ION RESONANCES AND THE DENSITY OF FREE-ELECTRON STATES - O-2 ISOLATED IN AN ARGON MATRIX, Physical review letters, 81(13), 1998, pp. 2807-2810
The lifetime of a negative ion resonance in the condensed phase and it
s impact on deposition of energy are investigated as a function of the
resonance energy. The variation in the energy deposited, which can be
measured in situ as an energy modulation of the vibrational scattered
intensities, is shown to correlate with the inverse of the density of
free electron states in the host medium. As an experimental model, we
studied O-2 embedded in an Ar matrix.