SURFACTANT CURVILINEAR DIFFUSION IN GIANT WORMLIKE MICELLES

We present the first experimental measurements of surfactant curviline ar diffusion in giant wormlike micelles. The surfactant diffusion was monitored by pulsed field gradient NMR for various observation times t ranging from 0.020 to 1.5 s. The surfactant mean-square displacement was found to scale as t(1/2). A model of lateral diffusion along worml ike micellar aggregates with Gaussian statistics is found to describe the echo attenuation well. This type of diffusion is analogous to poly mer segment diffusion in the tube-reptation model.