DEDIAZONIATION REACTIONS OF ARENEDIAZONIUM IONS UNDER SOLVOLYTIC CONDITIONS - FLUORIDE ANION ABSTRACTION FROM TRIFLUOROETHANOL AND ALPHA-HYDROGEN ATOM ABSTRACTION FROM ETHANOL

Authors
CANNING PSJ MCCRUDDEN K MASKILL H SEXTON B
Citation
Psj. Canning et al., DEDIAZONIATION REACTIONS OF ARENEDIAZONIUM IONS UNDER SOLVOLYTIC CONDITIONS - FLUORIDE ANION ABSTRACTION FROM TRIFLUOROETHANOL AND ALPHA-HYDROGEN ATOM ABSTRACTION FROM ETHANOL, Chemical communications, (18), 1998, pp. 1971-1972
Citations number
17
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
18
Year of publication
1998
Pages
1971 - 1972
Database
ISI
SICI code
1359-7345(1998):18<1971:DROAIU>2.0.ZU;2-B
Abstract
Arenediazonium salts decompose thermally and photochemically in triflu oroethanol to yield trifluoroethyl ethers and (in part by fluoride abs traction from the solvent) fluoroarenes; the less reactive compounds i n trifluoroethanol decompose readily in ethanol to give arenes in a ra dical reaction involving abstraction of the ct-hydrogen from the ethan ol.