STABILIZATION OF AN ENDIOLATE BY COORDINATION TO VANADIUM(IV)

Authors
FARAHBAKHSH M SCHMIDT H REHDER D
Citation
M. Farahbakhsh et al., STABILIZATION OF AN ENDIOLATE BY COORDINATION TO VANADIUM(IV), Chemical communications, (18), 1998, pp. 2009-2010
Citations number
34
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
18
Year of publication
1998
Pages
2009 - 2010
Database
ISI
SICI code
1359-7345(1998):18<2009:SOAEBC>2.0.ZU;2-D
Abstract
The redox reaction between [VCl2(tmeda)(2)] (tmeda = N,N,N',N'-tetrame thylenediamine) and benzil yielded the non-oxo V-IV benzoin complex [V (tmeda){Ph(O)C=C(O)Ph}(2)]. thf (C-2 symmetry), the first structurally characterised vanadium-endiolate complex.