SYNTHESIS AND CHARACTERIZATION OF A CHELATING 2-DIMETHYLSILYLPYRIDINECOMPLEX OF TITANOCENE(III)

Authors
HAO LJ WOO HG LEBUIS AM SAMUEL E HARROD JF
Citation
Lj. Hao et al., SYNTHESIS AND CHARACTERIZATION OF A CHELATING 2-DIMETHYLSILYLPYRIDINECOMPLEX OF TITANOCENE(III), Chemical communications, (18), 1998, pp. 2013-2014
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
18
Year of publication
1998
Pages
2013 - 2014
Database
ISI
SICI code
1359-7345(1998):18<2013:SACOAC>2.0.ZU;2-R
Abstract
The complex Cp2Ti[2-SiMe2(C5H4N)] 1, the first example of a chelating silyl, and a tertiary silyl complex of Cp2Ti(III), is prepared by reac tion of 2-SiHMe2(C5H4N) with Cp2TiMe2, and its X-ray structure, EPR sp ectrum and reactions with C5H5N and PMe3 are reported.