2,6-BIS(2,4,6-TRIISOPROPYLPHENYL)PHENYL AS AN EXTRAORDINARILY BULKY LIGAND IN ORGANOMETALLIC CHEMISTRY - SYNTHESIS AND MOLECULAR-STRUCTURE OF [(MES-ASTERISK-2C6H3)MCL2](2) (M = GA, IN, MES-ASTERISK = C6H2PR3I-2,4,6)
Jr. Su et al., 2,6-BIS(2,4,6-TRIISOPROPYLPHENYL)PHENYL AS AN EXTRAORDINARILY BULKY LIGAND IN ORGANOMETALLIC CHEMISTRY - SYNTHESIS AND MOLECULAR-STRUCTURE OF [(MES-ASTERISK-2C6H3)MCL2](2) (M = GA, IN, MES-ASTERISK = C6H2PR3I-2,4,6), Chemical communications, (18), 1998, pp. 2015-2016
Gallium chloride or indium chloride interacts with 2,6-bis(2,4,6-triis
opropylphenyl)phenyllithium, (Mes2C6H3)Li (Mes* = C6H2Pr3i-2,4,6), af
fording [(Mes2C6H3)MCl2](2) (M = Ga 1, In 2), interesting group 13 or
ganometallic crystalline dimers, characterized by elemental analyses,
H-1 and C-13 NMR spectroscopy, and single-crystal X-ray diffraction.