SYNTHESIS OF FLUORINE-CONTAINING CYCLIC AMINO-ACID DERIVATIVES VIA RING CLOSING OLEFIN METATHESIS

Authors
OSIPOV SN BRUNEAU C PICQUET M KOLOMIETS AF DIXNEUF PH
Citation
Sn. Osipov et al., SYNTHESIS OF FLUORINE-CONTAINING CYCLIC AMINO-ACID DERIVATIVES VIA RING CLOSING OLEFIN METATHESIS, Chemical communications, (18), 1998, pp. 2053-2054
Citations number
17
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
18
Year of publication
1998
Pages
2053 - 2054
Database
ISI
SICI code
1359-7345(1998):18<2053:SOFCAD>2.0.ZU;2-3
Abstract
New N-protected alpha-CF3 amino esters with two alkene chains (1,7-die nes 3 and 1,6-dienes 5) were reacted with the ring closing metathesis catalyst Ru=CHPh(Cl)(2)(PCy3)(2) to give the alpha-CF3 dehydropipecoli nate and prolinate derivatives 6 and 7.