Relying on the analysis conducted in the paper, the approaches are pro
posed for selecting the optimum temperature and cationic composition o
f the chloride melt and for determining the advisability of using mixe
d-ligand halide melts in the metal electrorefinement. By the example o
f neodymium, the efficiency of removing the rare-earth metal admixture
s as well as advantages and disadvantages of employing chloride-fluori
de melts as compared to chloride melts from the viewpoint of lowering
the content of admixtures of such metals-analogues as Y, La, Ce, and P
r are shown.