Jc. Kruithof et al., INTEGRATED MULTIOBJECTIVE MEMBRANE SYSTEMS FOR SURFACE-WATER TREATMENT - PRETREATMENT OF REVERSE-OSMOSIS BY CONVENTIONAL TREATMENT AND ULTRAFILTRATION, Desalination, 117(1-3), 1998, pp. 37-48
Within the scope of this project funded by AWWARF and USEPA three very
promising IMS's were identified for surface water treatment. This pap
er will cover some highlights of the research carried out by the Water
Supply Company of North Holland and Kiwa on the combination ultrafilt
ration/ultra low pressure reverse osmosis. Productivity of the ultrafi
ltration proved to be stable for the first 6000 h. Then, at the end of
summer, the backwash regime was not able to prevent accumulation of b
iofouling. This biofouling coincides with an increase in bacterial cou
nts in the ultrafiltrate. Also the ultra low pressure reverse osmosis
unit showed no significant fouling up to 6000 hours. Then a rapid decr
ease of the second stage MTC started caused by BaSO4 precipitation, co
inciding with an increase in feed-concentrate pressure drop caused by
a severe biofouling. Ultrafiltration reduced the indicator organisms E
. coli and spores of sulphite reducing Clostridia to under the detecti
on limit. To determine the elimination capacity the feed of UF and ULP
RO were spiked with MS-2 phages. Generally UF showed a complete (>5 lo
g) removal. Once only a 2.7 log removal was found caused by defects in
UF-membranes. ULPRO showed a high (4.7-4.9 log) although no complete
removal. The results show that integrity measurement and monitoring of
both membrane steps are essential. UF-integrity is measured by a pres
sure hold test and monitored by particle counting. integrity of ULPRO
is measured by vacuum testing and monitored by in situ conductivity me
asurement and particle counting. ULPRO gives a very high precursor rem
oval. Potential measurements (24 h, 20 degrees C, 1-2 mg/l Cl-2-residu
al) showed >95% removal of THMFP and HAAFP. IMS with UF and ULPRO are
exceptional tools for control of microbials and DBP-precursors. Crucia
l for application may be control of biofouling in the system.