SPECTROSCOPY AND DYNAMICS OF THE H-2-CN VAN-DER-WAALS COMPLEX

Authors
Citation
Yl. Chen et Mc. Heaven, SPECTROSCOPY AND DYNAMICS OF THE H-2-CN VAN-DER-WAALS COMPLEX, The Journal of chemical physics, 109(13), 1998, pp. 5171-5174
Citations number
26
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
ISSN journal
00219606
Volume
109
Issue
13
Year of publication
1998
Pages
5171 - 5174
Database
ISI
SICI code
0021-9606(1998)109:13<5171:SADOTH>2.0.ZU;2-I
Abstract
Spectra for the H-2-CN and D-2-CN complexes have been observed in asso ciation with the monomer B (2)Sigma(+)-X(2)Sigma(+) and A (2)Pi-X(2)Si gma(+) transitions. Ground state dissociation energies of D-0'' = 38+/ -1 cm(-1) (H-2-CN) and D-0'' = 42+/-1 cm(-1) (D-2-CN) were determined. Electronically nonadiabatic predissociations of H-2/D-2-CN(A) complex es were characterized using double resonance techniques. (C) 1998 Amer ican Institute of Physics. [S0021-9606(98)03437-0].