Vi. Anikeev et A. Ermakova, BINARY-INTERACTION COEFFICIENTS FOR THE REDLICH-KWONG-SOAVE EQUATION OF STATE, Theoretical foundations of chemical engineering, 32(5), 1998, pp. 462-467
Binary-interaction coefficients for the Redlich-Kwong-Soave equation o
f state are determined using experimental data on the vapor-liquid equ
ilibria in binary mixtures. The dependence of these coefficients on te
mperature and pressure is found. Example calculations of phase equilib
ria showed that the accuracy of the Redlich-Kwong-Soave model could be
improved, especially for the range of high pressures and temperatures
as well as near critical points.