Sp. Delineshev, GROWTH OF CRYSTALS IN PRESENCE OF IMPURITIES - A HYPOTHESIS BASED ON A KINETIC APPROACH, Crystal research and technology, 33(6), 1998, pp. 891-897
A hypothesis is proposed concerning the growth of crystals in the pres
ence of impurities soluble in the parent phase but insoluble in the cr
ystal. The hypothesis is based on: (i) a kinetic model developed by Bl
iznakov, where it is assumed that the impurity layers exert a passive
resistance towards the growth of crystals, (ii) results obtained by Ka
ischew concerning the nucleation of crystals on. foreign substrate; ac
cording to which the heterogeneous nucleation is more favourable than
the homogeneous one, in the presence of the same supersaturation, and
(iii) a statement of Distler and co-workers that a foreign intermediat
e layer contains ''single crystal'' structural information about the c
rystal face where the layer has been formed.