RHODIUM(I)-MEDIATED OR IRIDIUM(I)-MEDIATED EQUILIBRATED REACTIONS OF ACTIVATED 2,3-CIS-ALKYL-2-VINYLAZIRIDINE AND TRANS-3-ALKYL-2-VINYLAZIRIDINE

Authors
HONDA A OHNO H MIMURA N IBUKA T
Citation
A. Honda et al., RHODIUM(I)-MEDIATED OR IRIDIUM(I)-MEDIATED EQUILIBRATED REACTIONS OF ACTIVATED 2,3-CIS-ALKYL-2-VINYLAZIRIDINE AND TRANS-3-ALKYL-2-VINYLAZIRIDINE, Synlett, (9), 1998, pp. 969
Citations number
33
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
9
Year of publication
1998
Database
ISI
SICI code
0936-5214(1998):9<969:ROIERO>2.0.ZU;2-#
Abstract
Rhodium(I)- or iridium(I)-complexes-mediated equilibrated reactions of both 2,3-cis and 2,3-trans-N-arylsulfonyi-3-alkyl-2-vinylaziridines a fforded 2,3-cis- and trans-stereoisomeric mixtures in favor of 2,3-cis -isomers. Addition of a trialkyl phosphite such as trimethyl phosphite is critical to the equilibrated reactions. Important factors for the reactions are discussed.