DIRECTED PALLADIUM-CATALYZED CASCADE CYCLIZATION AS AN APPROACH TO TRANS-HEXAHYDRO-1H-BENZ[F]INDENE AND CIS-HEXAHYDRO-1H-BENZ[F]INDENE

Authors
COUDANNE I BALME G
Citation
I. Coudanne et G. Balme, DIRECTED PALLADIUM-CATALYZED CASCADE CYCLIZATION AS AN APPROACH TO TRANS-HEXAHYDRO-1H-BENZ[F]INDENE AND CIS-HEXAHYDRO-1H-BENZ[F]INDENE, Synlett, (9), 1998, pp. 998
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
9
Year of publication
1998
Database
ISI
SICI code
0936-5214(1998):9<998:DPCCAA>2.0.ZU;2-#
Abstract
The hydrogenation of the acetylenic substrate 6 followed by a palladiu m-catalyzed cascade bis-cyclization process led to a trans-hexahydro-1 H-benz[f]indene. By changing the order of the two preceding steps, onl y the cis-hexahydro-1H-benz[f]indene structure was obtained.