ENANTIOSELECTIVE CONSTRUCTION AND UTILIZATION OF 2-(CYCLOHEX-2-ENYL)PHENOLS

Authors
KONNO H OGASAWARA K
Citation
H. Konno et K. Ogasawara, ENANTIOSELECTIVE CONSTRUCTION AND UTILIZATION OF 2-(CYCLOHEX-2-ENYL)PHENOLS, Synlett, (9), 1998, pp. 1004
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
9
Year of publication
1998
Database
ISI
SICI code
0936-5214(1998):9<1004:ECAUO2>2.0.ZU;2-D
Abstract
Enantioselective construction of 2-(cyclohex-2-enyl)phenols from chira l equivalents of cyclohex-2-enols has been investigated by employing a concurrent retro-Diels-Alder reaction and Claisen rearrangement proto col. Utilizing the enantiomerically pure product obtained, the first e nantiocontrolled synthesis of a phenolic natural sesquiterpene (+)-cur cudiol isolated from the marine sponge Didiscus flavus, has been demon strated.