Y. Yoshida, MOSSBAUER-SPECTROSCOPY TO INVESTIGATE JUMP MECHANISMS ON ANATOMIC SCALE - FAST DIFFUSION STUDIES, Hyperfine interactions, 113(1-4), 1998, pp. 183-198
The fast diffusion of transition-metal impurities in metals and semico
nductors provides us with a challenging research field, because the ju
mp frequencies and the concentration of the ''diffusion vehicles'' (pr
obably interstitials) contributing to the fast diffusion are always cl
ose to the detection limit of Mossbauer spectroscopy. Therefore, sever
al new experimental set-ups have to be developed in order to achieve a
direct observation of the fast diffusing vehicles and to study the ju
mp mechanism on an atomic scale. High temperature UHV-furnaces and the
in-beam Mossbauer spectrometers, which have been constructed in diffe
rent institutes in different countries, are introduced and the new exp
erimental results obtained by these apparatus are presented.