NOTES ON ANALYTICAL FIGURES OF MERIT FOR CALIBRATION OF NTH-ORDER DATA

Authors
Citation
K. Faber, NOTES ON ANALYTICAL FIGURES OF MERIT FOR CALIBRATION OF NTH-ORDER DATA, Analytical letters, 31(13), 1998, pp. 2269-2278
Citations number
9
Categorie Soggetti
Chemistry Analytical
Journal title
ISSN journal
00032719
Volume
31
Issue
13
Year of publication
1998
Pages
2269 - 2278
Database
ISI
SICI code
0003-2719(1998)31:13<2269:NOAFOM>2.0.ZU;2-6
Abstract
A recently proposed framework for analytical figures of merit for nth- order data is discussed. A simple proof is provided that shows that fo r calculation of these performance characteristics the data is unfolde d to a vector (1st-order data). In doing so the special structure of t he data is not respected, which <(may)under bar> lead to inconsistenci es. The practical and theoretical implications of this observation are outlined. Theoretical ideas are illustrated with respect to a recentl y published application of excitation-emission fluorescence spectrosco py.