PHOTOREDUCTION OF IRC1(6)(2-) COMPLEX IN ALCOHOL-SOLUTIONS AND ITS REACTION WITH HYDROXYALKYL RADICALS

Authors
GLEBOV EM PLYUSNIN VF GRIVIN VP IVANOV YV TKACHENKO NV LEMMETYINEN H
Citation
Em. Glebov et al., PHOTOREDUCTION OF IRC1(6)(2-) COMPLEX IN ALCOHOL-SOLUTIONS AND ITS REACTION WITH HYDROXYALKYL RADICALS, International journal of chemical kinetics, 30(10), 1998, pp. 711-719
Citations number
50
Categorie Soggetti
Chemistry Physical
Journal title
International journal of chemical kinetics → ACNP
ISSN journal
05388066
Volume
30
Issue
10
Year of publication
1998
Pages
711 - 719
Database
ISI
SICI code
0538-8066(1998)30:10<711:POICIA>2.0.ZU;2-7
Abstract
The photochemistry of IrCl62- complex in simple alcohols have been stu died using laser-flash photolysis. Single electron transfer from the s olvent molecule to the light-excited complex has been shown to be the primary photochemical process. Quantum yields of the photoreduction of IrCl62- complex and the rate constants of its reaction with hydroxyal kyl radicals were determined at 200-330 KI Deviations of the rate cons tants from Debye-Smoluchowski equation for diffusion-controlled reacti ons are discussed. (C) 1998 John Wiley & Sons, Inc.