The electron ionization mass spectrometric behaviour of a series of di
ethylindium complexes with imino ligands derived from piperidine, pyrr
olidine, azetidine, methylaziridine and dicyclopropylamine were invest
igated. These data have been compared with those from mass-analysed io
n kinetic energy spectrometry. Fragmentation patterns of the complexes
in question give information relevant to their gas-phase behaviour as
precursors for III-V semiconducting materials via metal-organic chemi
cal vapour deposition. A comparison with analogous derivatives of dime
thylindium is also discussed. (C) 1998 John Wiley & Sons, Ltd.