CHIROPTICAL PROPERTIES OF HETEROTRIMETALLIC WING-TIP BUTTERFLIES - SYNTHESIS AND CRYSTAL-STRUCTURE OF (MU-H)RU2FE2PDC(CO)(12)(ETA(3)-BETA-C10H15)

Authors
GUBIN SP KLYAGINA AP GOLOVANEVA IF GALUZINA TV BELYAKOVA OA ZUBAVICHUS YV SLOVOKHOTOV YL
Citation
Sp. Gubin et al., CHIROPTICAL PROPERTIES OF HETEROTRIMETALLIC WING-TIP BUTTERFLIES - SYNTHESIS AND CRYSTAL-STRUCTURE OF (MU-H)RU2FE2PDC(CO)(12)(ETA(3)-BETA-C10H15), Inorganica Chimica Acta, 280(1-2), 1998, pp. 275-281
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
280
Issue
1-2
Year of publication
1998
Pages
275 - 281
Database
ISI
SICI code
0020-1693(1998)280:1-2<275:CPOHWB>2.0.ZU;2-T
Abstract
HRu2Fe2PdC(CO)(12)(eta(3)-beta-C10H15) cluster was prepared in the rea ction of (Et4N)[HFe2Ru2C(CO)(12)] With [Pd(eta(3)-beta-C10H15)Cl](2) X -ray structural study of HRu2Fe2PdC(CO)(12)(eta(3)-beta-C10H15) (where beta-C10H15, is beta-pinenyl) revealed a wing-tip butterfly geometry of the metal core and (1R, 2S, 3S, 5R) absolute configuration for both crystallographically independent molecules in the crystal. Chiroptica l properties of this cluster are compared with other clusters containi ng a Pd(eta(3)-beta-C10H15) fragment and discussed. (C) 1998 Elsevier Science S.A. All rights reserved.