MACROPOLYHEDRAL BORON-CONTAINING CLUSTER CHEMISTRY - THE [S2B18H19](-) ANION, AND THE REVERSIBLE DISMANTLING AND REGENERATION OF AN APICAL BORON CLUSTER SITE WITH CLUSTER CONNECTIVITY 6

Authors
JELINEK T CISAROVA I STIBR B KENNEDY JD THORNTONPETT M
Citation
T. Jelinek et al., MACROPOLYHEDRAL BORON-CONTAINING CLUSTER CHEMISTRY - THE [S2B18H19](-) ANION, AND THE REVERSIBLE DISMANTLING AND REGENERATION OF AN APICAL BORON CLUSTER SITE WITH CLUSTER CONNECTIVITY 6, Journal of the Chemical Society. Dalton transactions, (18), 1998, pp. 2965-2967
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
18
Year of publication
1998
Pages
2965 - 2967
Database
ISI
SICI code
0300-9246(1998):18<2965:MBCC-T>2.0.ZU;2-R
Abstract
The double-cluster [S2B18H19]- anion, from the [syn-B18H21](-) anion a nd elemental sulfur, has an eleven-vertex arachno-type subcluster with a {B-7} hexagonal planar-based pyramidal feature that reversibly disa ssembles and reassembles upon protonation followed by deprotonation.