Mossbauer spectroscopy is used to monitor the Tm-169 quadrupole intera
ction for the superconductor TmBa2Cu4O8 as a function of temperature.
Qualitative comparison with other Tm-169 results supports earlier clai
ms that the Tm3+ rank-2 crystal-field contribution lies between that f
or TmBa2Cu3O7 and that for TmBa2Cu3O6. However, there is quantitative
disagreement with crystal-field parameters determined elsewhere for Ho
Ba2Cu4O8.