Jc. Fitzmaurice et al., LOW-TEMPERATURE ROUTES TO EARLY TRANSITION-METAL NITRIDES, Journal of the Chemical Society. Dalton transactions, (16), 1993, pp. 2435-2438
Thermal initiation of the reaction of lithium nitride with anhydrous t
ransition-metal halides produces crystalline transition-metal nitrides
of various compositions M(x)N(y) (M = Y, La, Ti, Zr, Hf, V, Nb, Ta, C
r or Mn) via an exothermic solid-state metathesis reaction. Reaction o
f anhydrous late transition-metal halides with lithium nitride produce
s the metal (M = Mo, W, Fe, Co, Ni, Cu, Pt, Zn or Cd), dinitrogen and
lithium halide. The metal nitrides were purified by tetrahydrofuran tr
ituration and characterised by X-ray powder diffraction, scanning elec
tron microscopy, energy dispersive analysis with X-rays, magnetic mome
nt measurements, FTIR spectroscopy and microanalysis.