CHEMICAL-TRANSFORMATIONS OF SOLVENT-DERIVED OZONOLYSIS PRODUCTS - IMPROVED SYNTHESIS OF POLYCYCLIC 1,2,4,6-TETROXEPANES FROM ALPHA-ALKOXY ALPHA'-HYDROPEROXY CYCLIC ETHERS AND ALDEHYDES

Authors
MCCULLOUGH KJ USHIGOE Y TANAKA S MASUYAMA A NOJIMA M
Citation
Kj. Mccullough et al., CHEMICAL-TRANSFORMATIONS OF SOLVENT-DERIVED OZONOLYSIS PRODUCTS - IMPROVED SYNTHESIS OF POLYCYCLIC 1,2,4,6-TETROXEPANES FROM ALPHA-ALKOXY ALPHA'-HYDROPEROXY CYCLIC ETHERS AND ALDEHYDES, Journal of the Chemical Society. Perkin transactions. I (Print), (18), 1998, pp. 3053-3057
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I (Print) → ACNP
ISSN journal
0300922X
Issue
18
Year of publication
1998
Pages
3053 - 3057
Database
ISI
SICI code
0300-922X(1998):18<3053:COSOP->2.0.ZU;2-0
Abstract
alpha-Alkoxy alpha'-hydroperoxy cyclic ethers condense with aliphatic aldehydes under acidic conditions to produce the bicyclic 1,2,4,6-tetr oxepanes. By X-ray crystallographic analysis, the tetroxepanes 5b and 12b, derived from cyclocondensation of the hydroperoxides 4 and 8 resp ectively with acetaldehyde, were shown to be exo-isomers.