A STABLE 3-COORDINATE RHODIUM(I) OLEFIN COMPLEX

Authors
BUDZELAAR PHM DEGELDER R GAL AW
Citation
Phm. Budzelaar et al., A STABLE 3-COORDINATE RHODIUM(I) OLEFIN COMPLEX, Organometallics, 17(19), 1998, pp. 4121-4123
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
17
Issue
19
Year of publication
1998
Pages
4121 - 4123
Database
ISI
SICI code
0276-7333(1998)17:19<4121:AS3ROC>2.0.ZU;2-9
Abstract
Reaction of LLi (L = ArNC(Me)CHC(Me)NAr, Ar = 2,6-Me2C6-H-3) with [Rh( COE)(2)Cl](2) (COE = cyclooctene) produces stable, three coordinate LR h(COE) (1). At room temperature in solution, the LRh, fragment moves r apidly over one face of the COE ligand via reversible allyl hydride fo rmation.