FORMATION OF VERY WEAKLY INTERACTING ORGANOMETALLIC CATION-ANION SYSTEMS USING PEARSONS HSAB CONCEPT - SYNTHESIS AND STRUCTURES OF [AG(TOLUENE)(3)](-) AND [ALF2(THF)(4)](+) [((SIME3)(3)C)(2)AL2F5](-)() [(((SIME3)(3)C)(2)AL2F5)(2)LI]()

Authors
HATOP H ROESKY HW LABAHN T ROPKEN C SHELDRICK GM BHATTACHARJEE M
Citation
H. Hatop et al., FORMATION OF VERY WEAKLY INTERACTING ORGANOMETALLIC CATION-ANION SYSTEMS USING PEARSONS HSAB CONCEPT - SYNTHESIS AND STRUCTURES OF [AG(TOLUENE)(3)](-) AND [ALF2(THF)(4)](+) [((SIME3)(3)C)(2)AL2F5](-)() [(((SIME3)(3)C)(2)AL2F5)(2)LI](), Organometallics, 17(19), 1998, pp. 4326-4328
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
17
Issue
19
Year of publication
1998
Pages
4326 - 4328
Database
ISI
SICI code
0276-7333(1998)17:19<4326:FOVWIO>2.0.ZU;2-A
Abstract
By using Pearson's HSAB principle [Ag(Toluene)(3)](+) [{((SiMe3)(3)C)( 2)Al2F5}(2)Li](-) (2) has been synthesized from the reaction of [(SiMe 3)(3)CalF(2)](3) (1) with AgF and LiCl. Reaction of 1 with AgF2 and NH 4F affords [AlF2(THF)(4)](+) [{(SiMe3)(3)C}Al2F5](-) (3) and [NH4](+) [(SiMe3)(3)CalF(3)](-) (4), respectively. 2 and 3 have been structural ly characterized.