K. Chylinski et J. Gregorowicz, SOLUBILITIES OF (1-HEXANOL, OR 1,2-HEXANEDIOL, OR 2-HYDROXYPROPANOIC ACID ETHYL-ESTER, OR 2-HYDROXYHEXANOIC ACID ETHYL-ESTER) IN SUPERCRITICAL CO2, Journal of Chemical Thermodynamics, 30(9), 1998, pp. 1131-1140
Solubilities of 1-hexanol, or 1,2-hexanediol, or 2-hydroxypropanoic ac
id ethyl ester, or 2-hydroxyhexanoic acid ethyl ester in supercritical
CO2 have been measured at T=(311, 318, and 323, or 328)K in the press
ure range from 1 MPa to 8 MPa. The measurements have been performed us
ing a flow-type equipment coupled with a novel analytical procedure. A
n accurate correlation method for the solubility of low volatile subst
ances in supercritical CO2 based on the equilibrium condition for the
solute has I,een proposed and successfully applied for the interpolati
on of our experimental results. (C) 1998 Academic Press.