The roles of liquid bridging and particle surface washing with a surfa
ctant have been demonstrated using Geldart D particles undergoing arti
ficially induced cohesive gas-solid fluidization with thin-oil films.
It has been shown that a number of factors, including the amount of li
quid present and the liquid-solid contact angle, influence the interpa
rticle bonding. The fluidization behaviour, including minimum fluidiza
tion velocity, has been found to depend on liquid bonding, which is a
function of both the liquid and particle surface properties. Treatment
of particles with a surfactant raises the liquid-solid contact angle,
thereby decreasing the capillary forces. The results of this work dem
onstrate that this effect may be more significant than viscosity at co
nditions between minimum bubbling and minimum fluidization. This confi
rms that static bridge forces, dominated by capillary pressures and su
rface tension, control fluidization under low velocity conditions. Sur
face tension forces also play a significant role during bubbling and s
lugging behaviour, but at these higher gas velocities, binder viscosit
y increases in importance.The disadvantage of gas by-passing in fluidi
zed beds has been shown to be a phenomenon which is subject to manipul
ation. It has been demonstrated that controlled, and minimal liquid ad
dition to a gas-solid fluidized bed reduces the bubble size and averag
e bed voidage with little apparent agglomeration. These results confir
m that more investigation is required in the design of fluidized beds
where intimate gas-solid contacting is required.